PART I. INTRODUCTION 1) Stereoselective Glycosylations - Additions to Oxocarbenium Ions 2) Application of Armed, Disarmed, Superarmed, and Superdisarmed Building Blocks in Stereocontrolled Glycosylation and Expeditious Oligosaccharide Synthesis 3) Solvent Effect on Glycosylation PART II. STEREOCONTROLLED APPROACHES TO GLYCAN SYNTHESIS 4) Intramolecular Aglycon Delivery toward 1,2-cis Selective Glycosylation 5) Chiral Auxiliaries in Stereoselective Glycosylation Reactions 6) Glycosylation with Glycosyl Sulfonates PART III. CATALYTIC ACTIVATION OF GLYCOSIDES 7) Stereoselective C-Glycosylation from Glycal Scaffolds 8) Brønsted- and Lewis-Acid-Catalyzed Glycosylation 9) Nickel-Catalyzed Stereoselective Formation of 1,2-cis-2-Aminoglycosides 10) Photochemical Glycosylation PART IV. REGIOSELECTIVE FUNCTIONALIZATION OF MONOSACCHARIDES 11) Regioselective Glycosylation Methods 12) Regioselective, One-Pot Functionalization of Carbohydrates PART V. STEREOSELECTIVE SYNTHESIS OF DEOXY SUGARS, FURANOSIDES, AND GLYCOCONJUGATE SUGARS 13) Selective Glycosylations with Deoxy Sugars 14) Selective Glycosylations with Furanosides 15) De novo Asymmetric Synthesis of Carbohydrate Natural Products 16) Chemical Synthesis of Sialosides sakriti opis